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<dc:title xml:lang="fr">Synthèse inothermale de réseaux hybrides multiferroïques</dc:title>
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<dc:subject xml:lang="fr">Réseaux hybrides</dc:subject>
<dc:subject xml:lang="fr">Imidazolium</dc:subject>
<dc:subject xml:lang="fr">Magnétisme</dc:subject>
<dc:subject xml:lang="fr">Ferroélectricité</dc:subject>
<dc:subject xml:lang="fr">Caractérisation</dc:subject>
<dc:subject xml:lang="en">Hybrid networks</dc:subject>
<dc:subject xml:lang="en">Imidazolium</dc:subject>
<dc:subject xml:lang="en">Magnetism</dc:subject>
<dc:subject xml:lang="en">Ferroelectricity</dc:subject>
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<tef:elementdEntree autoriteExterne="034762590" autoriteSource="Sudoc">Matériaux hybrides</tef:elementdEntree>
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<tef:elementdEntree autoriteExterne="031378307" autoriteSource="Sudoc">Métaux de transition -- Composés</tef:elementdEntree>
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<dcterms:abstract xml:lang="fr">Ce manuscrit présente la synthèse de nouveaux réseaux hybrides organiques/inorganiques à base de différents ligands imidazoliums. Trois ligands imidazoliums possédant chacun des caractéristiques spécifiques ont été synthétisés et utilisés avec l’objectif de parvenir à la formation de réseaux hybrides multiferroïques c’est-à-dire des réseaux qui possède à la fois un ordre magnétique et un ordre électrique. La modification du ligand a ainsi permis d’obtenir des composés répondant aux critères (de symétrie en particulier) à remplir pour la présence d’un ordre électrique. Pour construire le réseau inorganique magnétique nous avons travaillé sur la synthèse de composés à base de métaux de transition de la première série ou de lanthanides. L’ensemble des composés obtenus a été caractérisé par un ensemble de techniques (diffraction des rayons X, spectroscopie FTIR et UV-Vis, analyses thermiques et élémentaires). Les propriétés magnétiques, de luminescence et de ferroélectricité des composés ont aussi été étudiées.</dcterms:abstract>
<dcterms:abstract xml:lang="en">This thesis presents the syntheses of new hybrid coordination networks based on imidazolium ligands. Three kinds of ligands possessing their own features were synthesized and used with the main objective to obtain multiferroic hybrid networks meaning networks which display a magnetic order and a ferroelectric order. The modification of the ligand allowed to obtain compounds filling criteria (on the symmetry) for a ferroelectric order. The magnetic inorganic network was built due to the synthesis of compounds based on first row metals or lanthanides. All compounds were characterized by several techniques (X-rays diffraction, spectroscopic measurements, thermal and elemental analyses). Magnetic, luminescence and ferroelectric properties were also studied.</dcterms:abstract>
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