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<dc:title xml:lang="en">Evaluation of the mechanisms of trace elements transport (Pb, Rare Earth Elements,... ) and the elemental and isotopic fractionation (Ca and Sr) at the interface water-soil-plant</dc:title>
<dcterms:alternative xml:lang="fr">Évaluation des mécanismes de transport des éléments traces (Pb, REE, ...) et du fractionnement des rapports élémentaires et isotopiques (Ca et Sr) à l'interface eau, sol, plante</dcterms:alternative>
<dc:subject xml:lang="fr">Carbone et fonction organique</dc:subject>
<dc:subject xml:lang="fr">Ultra-filtration</dc:subject>
<dc:subject xml:lang="fr">Flux chimiques colloïdaux et dissous</dc:subject>
<dc:subject xml:lang="fr">Géochimie isotopique</dc:subject>
<dc:subject xml:lang="fr">Calcium et Strontium</dc:subject>
<dc:subject xml:lang="fr">Terres rares</dc:subject>
<dc:subject xml:lang="fr">Prélèvement racinaire</dc:subject>
<dc:subject xml:lang="fr">Activité bactérienne</dc:subject>
<dc:subject xml:lang="fr">Altération du sol</dc:subject>
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<dc:subject xml:lang="en">Organic functional groups</dc:subject>
<dc:subject xml:lang="en">Ultrafiltration</dc:subject>
<dc:subject xml:lang="en">Colloidal and dissolved chemical fluxes</dc:subject>
<dc:subject xml:lang="en">Isotope geochemistry</dc:subject>
<dc:subject xml:lang="en">Calcium and Strontium</dc:subject>
<dc:subject xml:lang="en">REE</dc:subject>
<dc:subject xml:lang="en">Uptake by root</dc:subject>
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<dcterms:abstract xml:lang="fr">Ce travail est axé sur l’étude d’un profil de sol et des solutions de sol prélevés sur une parcelle expérimentale couvertes d’épicéas. Tous ces échantillons proviennent du Bassin Versant du Strengbach (Observatoire HydroGéochimique de l’Environnement – OHGE), ont été échantillonnés à différentes profondeurs (5, 10, 30 et 60 cm) et durant la période comprise entre 2009 et 2013.Les caractérisations des extraits des sols par spectroscopie Infra-Rouge ont permis de mettre en évidence les modifications des groupements fonctionnels organiques avec la profondeur et que ces modifications ont une forte incidence sur le comportement des cations (majeurs et traces) dans le sol. Des expérimentations d’ultra-filtration ont permis d’identifier les flux colloïdaux et dissous du carbone organique ainsi que ceux des éléments majeurs et traces présents dans les solutions de sol. L’utilisation conjointe des traceurs isotopiques (87Sr/86Sr et δ44/40Ca) et chimiques (Terres Rares) ont mis en évidence des processus ayant lieu aux interfaces eau-sol-plante, comme le prélèvement racinaire ou l’altération des sols.</dcterms:abstract>
<dcterms:abstract xml:lang="en">This work is focused on the study of a profile of soil and soil solutions collected on an experimental plot covered with spruce. All these samples come from the watershed of the Strengbach (environment - OHGE Hydrogeochimique Observatory), were sampled at different depths (5, 10, 30 and 60 cm) and during the period between 2009 and 2013. Characterizations of soil extracts by infrared spectroscopy allowed to highlight changes in the organic functional groups with depth and that these changes have a significant impact on the behaviour of the cations (major and trace) in the soil. Ultrafiltration experiments helped to identify flows of colloidal and dissolved organic carbon as well as those of the major and trace-element present in soil solutions. The joint use of isotope tracers (87Sr / 86Sr and δ44 / 40 Ca) and chemical (Rare Earth Elements) have highlighted processes taking place at the water-soil-plant interface, as the uptake by root or soil alteration.</dcterms:abstract>
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