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<dc:title xml:lang="fr">Dépôts alignés de nanofils d'argent au sein de films multicouches pour des propriétés conductrices et optiques</dc:title>
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<dc:subject xml:lang="fr">Nanofils d’argent</dc:subject>
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<dcterms:abstract xml:lang="fr">Cette thèse est consacrée à l’élaboration de films de nanofils d’argent orientés à l’aide de la technique de pulvérisation à incidence rasante. Couplée à la technique de dépôt couche-par-couche, il est possible de réaliser des films composés de plusieurs couches de nanofils d’argent orientées dans des directions différentes. Les films ainsi formés sont étudiés pour réaliser d’une part des supports conducteurs et transparents ordonnés et d’autre part pour réaliser des structures chirales aux propriétés optiques particulières. Une première étude est menée sur l’influence des différents paramètres de pulvérisation. Ils seront optimisés pour réaliser, dans un premier temps les échantillons transparents et conducteurs, puis dans un second, des structures chirales. Une seconde partie consiste à l’étude de structures hélicoïdales composées de plusieurs couches orientées de nanofils d’argent. Le dichroïsme circulaire de ces échantillons est étudié en fonction de différents paramètres de structure. Enfin une étude consistera à comparer les performances en tant que surface transparente et conductrice, de films orientés et d’argent sans ordre de nanofils.</dcterms:abstract>
<dcterms:abstract xml:lang="en">This study consist in the elaboration of aligned films of silver nanowires by the Grazing Incidence Spraying (GIS) technique. Combined with the Layer-by-Layer (LbL) technique, it is possible to generate films composed of several aligned layers of silver nanowires with different directions of orientation. Optical and conductive properties of these films will be investigated to highlight the impact of these 3D ordered structures. The influence of different parameters of the GIS will be studied. These parameters will be optimized in ordrer to design samples for conductive and transparent films and to elaborate chiral structures. Chiral structures will be realized and their circular dichroism will be investigated in function of structural parameters. A last study will be realized about the influence of order for transparent and conductive electrodes by measuring performances of films with aligned and randomly deposed silver nanowires.</dcterms:abstract>
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